No, by design it's not possible to access a file other than via a path to it, allowing it would bypass access control so that would be a security flaw.
root can possibly do that by using tools such as debugfs (for ext4 file systems) on the block device containing the filesystem (if any) effectively bypassing the kernel to inspect the filesystem structure but doing that on a mounted filesystem is not necessarily reliable; or using kernel instrumentation such as systemtap or bpftrace, though that's likely to be non-portable even between two versions of a given kernel.
So you should use something like:
find /root/of/filesystem -xdev -inode 12345 -exec stat {} ';'
To find the path(s) leading to that file with that particular inode and call stat on them.
With GNU find, you can also use -printf to report stat(2) information about the file.
statcommand and then accepted an answer using thedebugfscommand (which is specific to ext4 filesystems). What's the actual question here?