Questions tagged [statistical-mechanics]
The study of large, complicated systems employing statistics and probability theory to extract average properties and to provide a connection between mechanics and thermodynamics.
7,306 questions
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Phase transition for first moments in the 2D random-bond Ising model
I have a very basic confusion about the 2D random-bond Ising model on a square lattice with Boltzmann weight
$$\omega(J_{ij},\sigma_j)=\prod_{ij}(1-p)^{\delta_{J_{ij}=1}} p^{\delta_{J_{ij}=-1}} e^{-\...
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Maxwell-Juttner distribution and its derivation
I am looking for good notes on the Maxwell-Juttner distribution and its derivation. I stumbled across this post Calculation of Maxwell-Juttner distribution integral but I was unable to find reference ...
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What causes the difference in the graphs showing the dependence of a molecule's potential energy on distance?
"The potential curve will have the shape shown in the figure above if the molecules approach each other in plane A along the line connecting their centers".
"If the molecules approach ...
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What does grand potential for $2D$ systems mean?
In $3D$ the grand potential $\Omega = -PV$ has a well-defined physical meaning. But for $2D$ systems what would $\Omega$ actually mean physically? Dimensionally speaking it looks like $\Omega = -\...
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Diffusion equation after one time-step [closed]
Consider the equation:
$$
\partial_tu=D\partial_{xx}^2u
$$
with reflecting boundary condition at $x=0$ and with $u(x,0)=\delta(x)$ as an initial distribution.
First question: How should I understand a ...
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Kolmogorov complexity in physics - applications [duplicate]
Has there been application of Kolmogorov complexity to physics? Shannon entropy has an interpretation from thermodynamics. In principle Kolmogorov complexity and Shannon entropy are the same but is ...
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Alternate statement for Liouville's theorem: Can you say that the relative velocity between any two representative points is zero?
So Liouville's theorem basically says the local density of representative points stays constant or that the flow of representative points resembles that of an incompressible fluid. Can you then say ...
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Reweighting method for Metropolis algorithm
I read the Wiki page about the reweighting procedure as a way to use Monte Carlo methods with the sign problem, but I'd like to know more about how this could be implemented in the Metropolis ...
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How to choose the initial state of the reverse trajectory when applying fluctuation theorems and calculating entropy production?
In the literature on fluctuation theorems and stochastic entropy production, I often find different choices for the initial state of the reverse trajectory. This choice seems to depend on how the ...
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Why can a change in randomness (entropy) be mathematically expressed as $\frac{Q_{rev}}{T}$?
The change in entropy of a system resulting from a thermodynamic process can be calculated as:
$$\Delta S = \frac{Q_{rev}}{T}$$
where $Q_{rev}$ is the heat evolved/absorbed in the process had it ...
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Confused about derivation - electron gas with binary collisions and impurities scattering
I am confused about a derivation for the behaviour of electrons in a conductor with binary collisions, and scattering due to static impurities. The derivation begins as follows:
The distribution ...
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When are $N$ particles in $D$ dimensions the same as 1 particle in $ND$ dimensions?
Here is the Hamiltonian for a particle moving in a 2-dimensional box:
$$
H = \frac{p_x^2}{2m} + \frac{p_y^2}{2m} + V_2(x,y) .
$$
Here is the Hamiltonian for two non-interacting particles moving in a 1-...
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What is the meaning of "knowing all the Green functions implies knowledge of the full theory"?
I have encountered many times the sentence in the title. Either written in books or told by more experienced friends, there seems to be a consensus that "If we know all Green functions of a ...
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Stochastic calculus clarification
In an introductory statistical physics class, the overdamped Langevin equation was introduced as: $\frac{dx}{dt} = \frac{1}{\gamma}\xi$, where $\xi$ is the white noise representing the fluctuations. ...
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How does one go from the short-time stochastic evolution of a single quantum trajectory to the ensemble master equation?
In the quantum-jump (Monte Carlo) method described in Quantum Optics by Gerry and Knight, consider a single-mode cavity field where photons are lost at rate $\gamma$. For a single trajectory $|\Psi\...
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Cumulant expansion in computing generating functional at third order
In Kerson Huang's Quantum Field Theory 2nd, p 278, the author introduces "cumulant expansion"
from
$$
\ln \langle e^x \rangle = \ln \sum_{n=0}^\infty \frac{\langle x^n \rangle}{n!} = \...
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Computing the ground state energy using perturbation theory?
I know that, in quantum statistical mechanics, the ground state energy of a system at finite temperature can be computed from the partition function:
$$Z_{\beta} = \sum_{n=0}^{\infty}e^{-\beta E_{n}} =...
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What is the average formula for interacting picture at positive temperature?
Although this looks a very simple question, it has been difficult to find an answer on textbooks since many of them develop the theory of interacting many particles for zero temperature and just ...
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How to derive Fourier-Laplace transform of random walk master equation on 2D lattice (Part 2)?
This question is linked with this question and is related to this paper.
The Fourier-Laplace transform is given by:
$$P(q,r,s)=\sum_{t=0}^{\infty}\sum_{m,n=-\infty}^{\infty}\frac{e^{iqm+irn}}{(1 + s)^{...
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Is the second law of thermodynamics only a statistical and emergent law or not?
According to this answer,
According to the Fluctuation Theorem one can derive a specific formulation of the Second Law of Thermodynamics as manifested in the statistical effects over large number of ...
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How to derive Fourier-Laplace transform of random walk master equation on 2D lattice (Part 1)?
I have certain gaps in clearly understanding the derivation given in this paper. Suppose a particle moves on a 2D lattice randomly. The probability of going in any one direction outb of four available ...
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Will gases contained inside a box eventually reach zero temperature?
Suppose I have some amount of gas inside an isolated box.
As the gas molecules continue colliding with box wall and each other, there will be a loss of energy due to these collisions.
So, will over ...
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Nuclear Magnetic Resonance interaction of individual $μ_i$ with $B_1$
In Nuclear Magnetic Ressonance (MRI purpose) I am trying to understand how the magnetic field perpendicular to $B_0$ with intensity $B_1$ which supposedly is time dependent (the magnetic field is ...
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Law of increasing entropy when the temperature is not well defined
In an isolated system with well defined initial and final states, we can argue that $\Delta S\geq{0}$ easily. Consider the system's initial and finial states are denotes by points $A,B$. Then the ...
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How to incorporate boundary conditions in mean field descriptions while deriving macroscopic equations from microscopic stochastic processes?
The question is linked to this question.
The microscopic stochastic processes are defined using homogeneous jump probabilities between sites. The assumption will be broken when we have physical ...