The generators of a given Lie group (describing the symmetry in this case) form a vector space (the tangent space, which is at $0$ the lie algebra of the Lie Group), hence you can take linear combinations of them. Maybe you are confused since you think, that boost and rotations are forming two separate groups and therefore is it unnatural to take linear combinations of generators of rotations with generators of boosts.
However, although the rotations form indeed a group as their own separately, the Lorentz boosts do not form a group as their own, they are coupled to the rotations, which can be seen by considering the commutator of two Boost-Generators $K^i,K^j$. It is given by $[K^i,K^j]=-i\epsilon^{ijk}J^k$. Hence, if one wishes to describe the structure describing the transformations generated by the boosts generators, one needs naturally to consider also rotations.
So there is a bigger structure combine both together. The generators of this bigger structure, containing both types of generators $J$ and $K$, are forming a vector space, hence you can take linear combinations.
Usually, the vector space is taken over the field $\mathbb{R}$(real scalar multiplication is allowed), however, you can also generalize this to the field $\mathbb{C}$ (also complex scalar multiplication is allowed).
It turns out that the step going to the complexified Lie-Algebra is even necessary since you want to look at representations of the Poincare-group on the projective Hilbert space (QM state are defined up to a global phase). One can show that the unitary projective representations of a Lie group $G$ can be expressed as the unitary representations of the double cover of $G$ (which will be reconstructed via the complexified Lie-Algebra) on the Hilbert space itself. You can find more about this via looking at "Bargmann's Theorem"