Let's have a labelled picture (source):

I'm going to fix $\overline{CD}=1$, i.e. we have a regular pentagon of side-length $1$ in the middle. Let $\omega=\overline{CH}$, so that we have an isosceles triangle with side-lengths $1,\omega,\omega$ and angles $36^{\circ},72^{\circ},72^{\circ}$. That means
by the cosine rule, $\omega=\dfrac{1}{\sqrt{2(1-\cos36^{\circ})}}$.
The green radius is $\dfrac{1+2\omega}{6}$.
Meanwhile, by constructing a right-angled triangle inside the regular pentagon, we get immediately that
the red radius is $\dfrac{1}{2\tan36^{\circ}}$.
By calculation, these numbers are
(red) $0.68819...$ and (green) $0.70611...$, so the answer is that green is larger.
I'm also trying to find a neat trick to show this without needing a calculator. Here's what I have so far, which looks pretty cool and might help someone to get further:
$$\text{ green }<\text{ red }\Leftrightarrow\frac{1+2\omega}{6}<\frac{1}{2\tan36^{\circ}}\Leftrightarrow(1+2\omega)\tan36^{\circ}<3$$
$$\Leftrightarrow\left(1+\frac{2}{\sqrt{2(1-\cos36^{\circ})}}\right)\frac{\sqrt{1-\cos^236^{\circ}}}{\cos36^{\circ}}<3$$
$$\Leftrightarrow\frac{\sin36^{\circ}+\sqrt{2(1+\cos36^{\circ})}}{\cos36^{\circ}}<3$$
The exact values of $\cos36^{\circ}$ and $\sin36^{\circ}$ are known:
$$\cos36^{\circ}=\frac{1+\sqrt{5}}{4}\qquad\text{ and }\qquad\sin36^{\circ}=\frac{\sqrt{10-2\sqrt{5}}}{4}$$
so we have
$$\text{ green }<\text{ red }\Leftrightarrow\frac{\sqrt{10-2\sqrt{5}}+2\sqrt{10+2\sqrt{5}}}{1+\sqrt{5}}<3\Leftrightarrow4\sqrt{5}<4$$
which resolves the question without need of a calculator (although it's still quite computational in a different way).