I always go to http://www.connectionstrings.com/ when I forget how a connectionstring is written.
Standard security SQL Server 2008
Data Source=myServerAddress;Initial Catalog=myDataBase;User Id=myUsername;Password=myPassword;
Here is an article on MSDN talking about How to: Read Connection Strings from the Web.config.
You have a section almost at the top in your Web.config called connectionstrings, it could look something like this:
<connectionStrings>
<add
name="NorthwindConnectionString"
connectionString="Data Source=serverName;Initial
Catalog=Northwind;Persist Security Info=True;User
ID=userName;Password=password"
providerName="System.Data.SqlClient"
/>
</connectionStrings>
I would recommend however that you also look in to Entity Framework which is an abstraction between your code and the database, it makes it easier to work with "objects" in your database. You can find an introduction to ADO.NET Entity Framework here. But first of all you should focus on getting your connection up and running to your database using the information at the top.