It is possible to create a column which would contain an array of bytea values, eg:
CREATE TABLE test ( id serial, images bytea[], .. other columns ...);
However, I would recommend creating a separate table to contain the images, for the following reasons:
It will provide greater flexibility when querying out the images
It will most likely perform better, when it comes to aspects such as updating the images, inserting an image, deleting images.
Depending on your use case, queries are likely to perform better as well.
The reason for the performance aspects is to do with how columns are stored. If the total size of a row is less than the page size (typically 8KB) then these columns are stored in-line. If the size exceeds 8KB, then the largest columns will be compressed and/or moved into separate "TOAST" tables.
If you store all of the images in an array inside the column, then:
From the database perspective, you will only ever be able to retrieve ALL of the images, not just one of them. Even though you can select a single image, the database will have to read all of them into memory to find that image for you.
If the size of the rows is <8kb (ie. if the images are small) then you won't even be able to query other table columns without the database reading the images into memory as well.
Adding, updating, or removing an image will result in all of the images getting rewritten (since they are all stored in an array).