Refer either to the element's .Text property or the .nodeTypeValue property :
Sub TestXML()
Dim xmlDoc As Object 'Or enable reference to Microsoft XML 6.0 and use: MSXML2.DOMDocument
Dim elements As Object
Dim el As Variant
Dim xml$
xml = "<?xml version=""1.0"" ?>"
xml = xml & "<DTS:Executable xmlns:DTS=""www.microsoft.com/abc"" DTS:ExecutableType=""xyz"">"
xml = xml & "<DTS:Property DTS:Name=""PackageFormatVersion"">3</DTS:Property>"
xml = xml & "<DTS:Property DTS:Name=""VersionComments"" />"
xml = xml & "<DTS:Property DTS:Name=""CreatorName"">FirstUser</DTS:Property>"
xml = xml & "<DTS:Property DTS:Name=""CreatorComputerName"">MySystem</DTS:Property>"
xml = xml & "</DTS:Executable>"
Set xmlDoc = CreateObject("MSXML2.DOMDocument")
'## Use the LoadXML method to load a known XML string
xmlDoc.LoadXML xml
'## OR use the Load method to load xml string from a file location:
'xmlDoc.Load "C:\my_xml_filename.xml"
'## Get the elements matching the tag:
Set elements = xmlDoc.getElementsByTagName("DTS:Property")
'## Iterate over the elements and print their Text property
For Each el In elements
Debug.Print el.Text
'## Alternatively:
'Debug.Print el.nodeTypeValue
Next
End Sub
I know some value is 3 but what that value is how could I know??
You can review the objects in the Locals window, and examine their properties:

Here is an alternative, which seems clunkier to me than using the GetElementsByTagName but if you need to traverse the document, you could use something like this:
Sub TestXML2()
Dim xmlDoc As MSXML2.DOMDocument
Dim xmlNodes As MSXML2.IXMLDOMNodeList
Dim xNode As MSXML2.IXMLDOMNode
Dim cNode As MSXML2.IXMLDOMNode
Dim el As Variant
Dim xml$
xml = "<?xml version=""1.0"" ?>"
xml = xml & "<DTS:Executable xmlns:DTS=""www.microsoft.com/abc"" DTS:ExecutableType=""xyz"">"
xml = xml & "<DTS:Property DTS:Name=""PackageFormatVersion"">3</DTS:Property>"
xml = xml & "<DTS:Property DTS:Name=""VersionComments"" />"
xml = xml & "<DTS:Property DTS:Name=""CreatorName"">FirstUser</DTS:Property>"
xml = xml & "<DTS:Property DTS:Name=""CreatorComputerName"">MySystem</DTS:Property>"
xml = xml & "</DTS:Executable>"
Set xmlDoc = CreateObject("MSXML2.DOMDocument")
'## Use the LoadXML method to load a known XML string
xmlDoc.LoadXML xml
'## OR use the Load method to load xml string from a file location:
'xmlDoc.Load "C:\my_xml_filename.xml"
'## Get the elements matching the tag:
Set xmlNodes = xmlDoc.ChildNodes
'## Iterate over the elements and print their Text property
For Each xNode In xmlDoc.ChildNodes
If xNode.NodeType = 1 Then ' only look at type=NODE_ELEMENT
For Each cNode In xNode.ChildNodes
Debug.Print cNode.nodeTypedValue
Debug.Print cNode.Text
Next
End If
Next
End Sub