EDITEDIT[1]
I add the output of the file -s command for a exfat partition and for an ext4 partition.
In these 4 examples (FAT32, NTFS, EXFAT, EXT4) the output of the file command appears very different for different filesystem types, so it is difficult to find a simple rule to decide the filesystem type by this output.
EDIT[2]
To clarify why I'm trying to use the file command to get information about the filesystem type of a USB, please read this post.