I think you don't want "-ExecutionPolicy","Unrestricted" as script arguments but instead want to set powershells execution policy to allow the execution of your script. Therefore you should pass those parameters before the actual Script.
Second: It's not enough, to pass the script as argument to powershell.exe (this way the script name is interpreted as Powershell command and one has to escape the name according to powershells quoting rules). Instead the Script name should be given after the -File parameter. From online documentation:
-File []
Runs the specified script in the local scope ("dot-sourced"), so that the functions and variables that the script creates are
available in the current session. Enter the script file path and any
parameters. File must be the last parameter in the command, because
all characters typed after the File parameter name are interpreted as
the script file path followed by the script parameters.
You can include the parameters of a script, and parameter values, in
the value of the File parameter. For example: -File .\Get-Script.ps1 -Domain Central
Typically, the switch parameters of a script are either included or
omitted. For example, the following command uses the All parameter of
the Get-Script.ps1 script file: -File .\Get-Script.ps1 -All
In rare cases, you might need to provide a Boolean value for a switch
parameter. To provide a Boolean value for a switch parameter in the
value of the File parameter, enclose the parameter name and value in
curly braces, such as the following: -File .\Get-Script.ps1 {-All:$False}.
Third: As cdarke already commented, it's better to use a list instead of a string as argument to Popen. This way one doesn't need to worry about the CommandLine parsing on Windows.
Altogether, this should be the way to go. (Tested with small test script.)
import subprocess
autom = r"C:\Users\mrmostacho\Desktop\Robot\Autom.ps1"
powershell = r"C:\Windows\System32\WindowsPowerShell\v1.0\powershell.exe"
subprocess.Popen([powershell,"-ExecutionPolicy","Unrestricted","-File", autom])
If you need to pass arguments to the script, do it like this:
subprocess.Popen([powershell,"-ExecutionPolicy","Unrestricted","-File", autom, 'arg 1', 'arg 2'])
Popenjust the path to PowerShell script by itself.startshell command (possibly you'll needshell=Truein thePopenconstructor as well). That should detach the launched process from the Python proces.